Bas de Bruin

Bas de Bruin

Prof. Dr. Bas de Bruin
Univ. of Amsterdam (UvA)
Dept. Homogeneous, Supramolecular & Bio-Inspired Catalysis
Science Park 904
1098 XH Amsterdam
The Netherlands
website, mail


Metals: Fe, Co, Ni, Pd, Ru, Rh, Ir
Techniques: EPR, DFT, NMR, IR, UV-vis, Electrochemistry, Magnetic susceptibility
Resources: X-band EPR (optical window, helium cryostat), DFT (ADF, Orca, Turbomole), NMR, IR, UV-vis, Electrochemistry, RT Magnetic susceptibility

Recent publications

M. Goswami, V. Lyaskovskyy, S.R. Domingos, W.J. Buma, S. Woutersen, O. Troeppner, I. Ivanović-Burmazović, H. Lu, X. Cui, X.P. Zhang, E.J. Reijerse, S. DeBeer, M.M. van Schooneveld, F. Pfaff, K. Ray, and B. de Bruin
"Characterization of Porphyrin-Co(III)-‘Nitrene Radical’ Species Relevant in Catalytic Nitrene Transfer Reactions"
J. Am. Chem. Soc. 2015 [abstract]
DOI: 10.1021/jacs.5b01197

S.H.A.M. Leenders, R. Gramage-Doria, B. de Bruin, and J.N.H. Reek
"Transition metal catalysis in confined spaces"
Chem. Soc. Rev. 2015, 44, 433-448 [abstract]
DOI: 10.1039/C4CS00192C

M. Otte, P.F. Kuijpers, O. Troeppner, I. Ivanović-Burmazović, J.N.H. Reek, and B. de Bruin
"Encapsulated Cobalt-Porphyrin as a Catalyst for Size-Selective Radical-type Cyclopropanation Reactions"
Chem. Eur. J. 2014, 20, 4880-4884 [abstract]
DOI: 10.1002/chem.201400055

S.R. Domingos, A. Huerta-Viga, L. Baij, S. Amirjalayer, D.A.E. Dunnebier, A.J.C. Walters, M. Finger, L.A. Nafie, B. de Bruin, W.J. Buma, and S. Woutersen
"Amplified Vibrational Circular Dichroism as a Probe of Local Biomolecular Structure"
J. Am. Chem. Soc. 2014, 136, 3530-3535 [abstract]
DOI: 10.1021/ja411405s

N.D. Paul, A. Chirila, H. Lu, X.P. Zhang, and B. de Bruin
"Carbene Radicals in Cobalt(II)-Porphyrin-Catalysed Carbene Carbonylation Reactions; A Catalytic Approach to Ketenes"
Chem. Eur. J. 2013, 19, 12953-12958 [abstract]
DOI: 10.1002/chem.201301731

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