Malcolm Halcrow
Contact
Prof. Malcolm Halcrow
Univ. of Leeds
School of Chemistry
Woodhouse Lane
Leeds LS2 9JT
UK
website,
mail
Expertise
Metals: Fe,
Co,
Cu,
and most other metals from groups 6-12
Techniques: Molecular synthesis, crystallography, magnetic measurements (including Evans method), EPR, electrochemistry
Resources: Synthesis lab, NMR, single crystal and powder X-ray diffraction, SQUID magnetometer, X-band EPR, voltammetry, DSC/TGA, UV/vis/NIR
Recent publications
M.A. Halcrow
"Structure:function relationships in molecular spin-crossover complexes"
Chem. Soc. Rev. 2011, 40, 4119-4142
[abstract]
DOI: 10.1039/c1cs15046d
V.A. Money, C. Carbonera, J. Elhaïk, M.A. Halcrow, J.A.K. Howard, and J. Létard
"Interplay Between Kinetically Slow Thermal Spin-Crossover and Metastable High-Spin State Relaxation in an Iron(II) Complex with SimilarT1/2 andT(LIESST)"
Chem. Eur. J. 2007, 13, 5503-5514
[abstract]
DOI: 10.1002/chem.200601312
T.D. Roberts, F. Tuna, T.L. Malkin, C.A. Kilner, and M.A. Halcrow
"An iron(ii ) complex exhibiting five anhydrous phases, two of which interconvert by spin-crossover with wide hysteresis"
Chem. Sci. 2012, 3, 349-354
[abstract]
DOI: 10.1039/c1sc00584g
R. Kulmaczewski, H.J. Shepherd, O. Cespedes, and M.A. Halcrow
"A Homologous Series of [Fe(H2 Bpz2 )2 (L)] Spin-Crossover Complexes with Annelated Bipyridyl Co-Ligands"
Inorg. Chem. 2014, 53, 9809-9817
[abstract]
DOI: 10.1021/ic501402q
L.J. Kershaw Cook, H.J. Shepherd, T.P. Comyn, C. Baldé, O. Cespedes, G. Chastanet, and M.A. Halcrow
"Decoupled Spin Crossover and Structural Phase Transition in a Molecular Iron(II) Complex"
Chem. Eur. J. 2015, 21, 4805-4816
[abstract]
DOI: 10.1002/chem.201406307