Christian Limberg
Contact
Prof. Dr. Christian Limberg
Humboldt-Universität zu Berlin
Dept. Chemistry
Brook-Taylor-Str. 2
12489 Berlin
Germany
website,
mail
Expertise
Metals:
FeII, FeIII,
NiI, NiII,
CrII-CrVI,
CuI, CuII,
MoIV-MoVI
Techniques: (i) Metal-oxygen systems:
a) Modeling of reactive metaloxo-surface species;
b) Biomimetic O2-Activation and Oxidation;
(ii) Activation of small substrates like N2, CO2 und H2 with the aid of dinculear complexes;
(iii) Molecular precursors for functional materials;
(iv) Special binding situations
Resources: GC/MS, ESI/MS, UV-Vis, Raman Spectrometer, closed cycle cooled 57Fe-Mössbauer
Recent publications
M. Sallmann, and C. Limberg
"Utilizing the Trispyrazolyl Borate Ligand for the Mimicking of O2 -Activating Mononuclear Nonheme Iron Enzymes"
Acc. Chem. Res. 2015, 48, 2734-2743
[abstract]
DOI: 10.1021/acs.accounts.5b00148
M. Sallmann, F. Oldenburg, B. Braun, M. Réglier, A.J. Simaan, and C. Limberg
"A Structural and Functional Model for the 1-Aminocyclopropane-1-carboxylic Acid Oxidase"
Angew. Chem. Int. Ed. 2015, 54, 12325-12328
[abstract]
DOI: 10.1002/anie.201502529
F. Schax, S. Suhr, E. Bill, B. Braun, C. Herwig, and C. Limberg
"A Heterobimetallic Superoxide Complex formed through O2 Activation between Chromium(II) and a Lithium Cation"
Angew. Chem. Int. Ed. 2015, 54, 1352-1356
[abstract]
DOI: 10.1002/anie.201409294
P. Haack, A. Kärgel, C. Greco, J. Dokic, B. Braun, F.F. Pfaff, S. Mebs, K. Ray, and C. Limberg
"Access to a CuII –O–CuII Motif: Spectroscopic Properties, Solution Structure, and Reactivity"
J. Am. Chem. Soc. 2013, 135, 16148-16160
[abstract]
DOI: 10.1021/ja406721a
S. Pfirrmann, C. Limberg, C. Herwig, C. Knispel, B. Braun, E. Bill, and R. Stösser
"A Reduced β-Diketiminato-Ligated Ni3 H4 Unit Catalyzing H/D Exchange"
J. Am. Chem. Soc. 2010, 132, 13684-13691
[abstract]
DOI: 10.1021/ja106266v
