Kallol Ray

Kallol Ray
Leader Working Group 4

Dr. Kallol Ray
Humboldt-University Berlin
Synthetic Bioinorganic Chemistry
Brook-Taylor Strasse 2
12489 Berlin
website, mail


Metals: Fe, Co, Ni, Cu
Techniques: Synthesis, Kinetics, High-Valent Metal-Oxo, Metal-Nitrenes, Dioxygen activation, water oxidation
Resources: UV-Vis fitted with cryostat (-100 to +100 °C), X-ray absorption spectroscopy

Recent publications

Florian Heims, Florian Felix Pfaff, Sarah-Luise Abram, Erik R. Farquhar, Maurizio Bruschi, Claudio Greco, Kallol Ray
"Redox Non-Innocence of a N-Heterocyclic Nitrenium Cation Bound to a Nickel-Cyclam Core"
J. Am. Chem. Soc. 2014, 136, 582-585 [abstract]
DOI: 10.1021/ja4099559

Sarah-Luise Abram, Inés Monte-Pérez, Florian Felix Pfaff, Erik R. Farquhar, Kallol Ray
"Evidence of two-state reactivity in alkane hydroxylation by Lewis-acid bound copper–nitrene complexes"
Chem. Commun. 2014, 50, 9852-9854 [abstract]
DOI: 10.1039/c4cc03754e

Subrata Kundu, Florian Felix Pfaff, Enrico Miceli, Ivelina Zaharieva, Christian Herwig, Shenglai Yao, Erik R. Farquhar, Uwe Kuhlmann, Eckhard Bill, Peter Hildebrandt, Holger Dau, Matthias Driess, Christian Limberg, Kallol Ray
"A High-Valent Heterobimetallic [CuIII(μ-O)2NiIII]2+ Core with Nucleophilic Oxo Groups"
Angew. Chem. Int. Ed. 2013, 52, 5622-5626 [abstract]
DOI: 10.1002/anie.201300861

Subrata Kundu, Enrico Miceli, Erik Farquhar, Florian Felix Pfaff, Uwe Kuhlmann, Peter Hildebrandt, Beatrice Braun, Claudio Greco, Kallol Ray
"Lewis Acid Trapping of an Elusive Copper–Tosylnitrene Intermediate Using Scandium Triflate"
J. Am. Chem. Soc. 2012, 134, 14710-14713 [abstract]
DOI: 10.1021/ja306674h

Florian Felix Pfaff, Subrata Kundu, Marcel Risch, Shanthi Pandian, Florian Heims, Iweta Pryjomska-Ray, Peter Haack, Ramona Metzinger, Eckhard Bill, Holger Dau, Peter Comba, Kallol Ray
"An Oxocobalt(IV) Complex Stabilized by Lewis Acid Interactions with Scandium(III) Ions"
Angew. Chem. Int. Ed. 2011, 50, 1711-1715 [abstract]
DOI: 10.1002/anie.201005869

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